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Creators/Authors contains: "Kayser, Ann K"

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  1. ; ; ; ; (, Inorganic Chemistry)
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  2. ; ; ; ; ; (, Chemical Communications)
    The exposure of CrCl 2 (THF) 2 to 1 equiv. of TEMPO and 1 equiv. [TEMPO]Na afforded (η 2 -O,N-TEMPO) 2 CrCl (1, 67%); addition of [TEMPO]Na to 1 yielded (η 2 -O,N-TEMPO) 2 Cr(TEMPO) (2). Both 1 and 2 exhibit pseudo-pentagonal planar (PPP) geometry, instead of myriad alternatives. Calculations and spectral studies suggest the solid-state geometry persists in solution. 
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